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Spin-Bearing Ligands Based on the 1,2,3-Dithiazole

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Title: Spin-Bearing Ligands Based on the 1,2,3-Dithiazole
Author: Carello, Christian E
Department: Department of Chemistry
Program: Chemistry
Advisor: Preuss, Kathryn E
Abstract: A 1,2,3-dithiazolyl radical, [1,2,3]dithiazolyl[4,5-f][1,10]phenanthroline, has been prepared and characterized. The EPR spectrum in toluene supports a delocalized structure with an experimental g-factor of 2.0081. Cyclic voltammetry in CH2Cl2 reveals an Ecell of 1.30 V vs. SCE with a reversible +1/0 and irreversible 0/-1 redox couple. The structure belongs to the space group P-1. Complexes of the radical with Mn2+ and Dy3+ have been obtained. The mononuclear Mn2+ complex was confirmed by elemental analysis; however, no structure was determined. The structure of the mononuclear Dy3+ complex was determined by X-ray crystallography and belongs to the space group C2/c. An isopropyl-substituted oxobenzene-bridged bis-1,2,3-dithiazolyl radical has been prepared and characterized by EPR and cyclic voltammetry. The EPR in toluene supports a delocalized structure with an experimental g-factor of 2.0091. Cyclic voltammetry in CH3CN reveals an Ecell of 0.64 V vs SCE with a reversible +1/0 and irreversible 0/-1 and +2/+1 redox couples.
URI: http://hdl.handle.net/10214/4874
Date: 2012-12
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