SEIRAS Studies of Water Structure in a Sodium Dodecyl Sulfate film adsorbed at a Gold Electrode Surface

Date

Mar-15

Authors

Grossutti, M.
Leitch, J.J.
Seenath, R.
Karaskiewicz, M.
Lipkowski, J.

Journal Title

Journal ISSN

Volume Title

Publisher

ACS Publications

Abstract

Surface enhanced infrared reflection absorption spectroscopy (SEIRAS) was used to investigate the structure of water that is incorporated within a film of sodium dodecyl sulfate (SDS) adsorbed at a thin gold nanoparticles film deposited onto a silicon substrate. Previous studies on a Au(111) electrode surface showed that SDS molecules form long range ordered hemi-cylindrical hemi-micelles (phase I) for potentials -0.2 ≤ E ≤ 0.45 V vs. Ag/AgCl and disordered bilayer (phase II) for potentials E ≥ 0.5 V vs. Ag/AgCl. The SEIRA spectra demonstrated that the hemi-micellar film is water rich and contains both a network of hydrogen bonded water and a disturbed network of hydrogen bonds consisting of monomeric and dimeric water in the hydrophobic region of the film. No network water was observed in phase II of the film. However, SEIRAS data showed that sulfate groups in the disordered bilayer are hydrated. The SEIRAS spectra of the film of SDS were compared to the previously measured spectra 2 obtained using subtractively normalized interfacial Fourier transform IR spectroscopy (SNIFTIRS). The complementarity of the spectroscopic information obtained by these two techniques was demonstrated.

Description

This document is the Accepted Manuscript version of a Published Work that appeared in final form in Langmuir, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.langmuir.5b00343

Keywords

SEIRAS, Sodium dodecyl sulfate, Hydrogen bonded water

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