Investigation of the Proposed of Air-Stable Magnetic Plastic Crystal and the Novel Design of Benzo[e][1,2,4]Triazine Bending Crystals

dc.contributor.advisorKathryn, Preuss
dc.contributor.authorRaouf, Farroq
dc.date.accessioned2022-08-16T18:17:00Z
dc.date.copyright2022-08-11
dc.date.created2022-08-11
dc.degree.departmentDepartment of Chemistryen_US
dc.degree.grantorUniversity of Guelphen
dc.degree.nameMaster of Scienceen_US
dc.degree.programmeChemistryen_US
dc.description.abstractThis thesis describes the synthesis and design of novel benzo[e][1,2,4]triazine crystals (known as F-C8-BTriaz, Cl-C8-BTriaz, and Br-C8-BTriaz), in which selective change of a halogen atom at the C8 position results in mechanical flexibility. Through developmental understanding of organic plastic and elastic crystals, the rational and explanation of flexibility and brittleness of F-C8-BTriaz, Cl-C8-BTriaz, and Br-C8-BTriaz is elucidated. F-C8-BTriaz and Cl-C8-BTriaz display mechanical flexibility with differing packing arrangements, whilst Br-C8-BTriaz mainly exhibits brittleness as a crystal. Alongside the synthesis of novel benzo[e][1,2,4]triazine crystals, attempts were made at synthesizing a novel Blatter radical (classified as O-Blatter-Me-BTriaz) that was postulated to exhibit mechanical flexibility as a single crystal. A discussion into the synthetic protocols and issues in synthesizing O-Blatter-Me-BTriaz is presented as O-Blatter-Me-BTriaz was never obtained in large quantities.en_US
dc.description.embargo2023-08-11
dc.identifier.urihttps://hdl.handle.net/10214/27107
dc.language.isoenen_US
dc.publisherUniversity of Guelphen
dc.rights.licenseAll items in the Atrium are protected by copyright with all rights reserved unless otherwise indicated.
dc.subjectMechanically flexibleen_US
dc.subjectbenzo[e][1,2,4]triazineen_US
dc.subjecthalogenateden_US
dc.subjectsingle organic crystalsen_US
dc.titleInvestigation of the Proposed of Air-Stable Magnetic Plastic Crystal and the Novel Design of Benzo[e][1,2,4]Triazine Bending Crystalsen_US
dc.typeThesisen

Files

Original bundle
Now showing 1 - 1 of 1
Loading...
Thumbnail Image
Name:
Raouf_Farroq_202208_MSc.pdf
Size:
4.05 MB
Format:
Adobe Portable Document Format
Description: